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Sam Page and Blake Lively Pictures: Gossip Girl Filming August 31, 2010 Photos and Pics

Sam Page and Blake Lively Pictures: Sam Page and Blake Lively seen on the set of "Gossip Girl" filming on location in the Meatpacking district on August 31, 2010 in New York City.

The "Desperate Housewives" and "Mad Men" hunk is joining the "Gossip Girl" cast for a multi-episode arc as Serena's (Lively) new love interest. Page's first episode will likely air in October.

"Gossip Girl" kicks off its fourth season on Sept. 13.

Photo credit: Janet Mayer / PR Photos