The first thing we thought when we saw Angelina Jolie in this sophisticated white dress at the London premiere of her new film Unbroken? It looks like something Scandal‘s Olivia Pope would wear. From the sleek bolero cape to the midi hemline to the button detailing down the back, the actress’s custom Ralph & Russo design would look just as good in Washington, D.C. as it does on the red carpet.

Fred Duval/FilmMagic (2)

So is Jolie a Scandal fan? We’d guess yes, because who isn’t? But really, we just wanted to talk about her flawless play on winter white at Tuesday’s premiere. The star has collaborated with designers Tamara Ralph and Michael Russo (founders of the London-based brand Ralph & Russo) in the past on looks like this white peplum design. At the time, the designers told PEOPLE that Jolie loves “going through the design process,” and her “personality is so lovely, and it really radiates that beauty.”

RELATED PHOTOS: Weigh in on the latest red carpet moments

The Oscar winner accessorized her latest look with diamond-accented gold Beladora hoops, nude pumps, a floral poppy pin and a sleek swept-back updo.

What do you think of Jolie’s latest look? Is it a personal best for the star? Sound off below.

–Brittany Talarico